For those of us who've never received formal volleyball coaching it's hard to properly learn the fundamentals of the game without getting into some really bad habits.
Kudda: Volleyball
I found this site full of videos which cover many topics: Passing, Defense, Attacking, Setting, Serving, Blocking...
Divided up into "clinics" which group videos together; they cover everything including fundamentals, training & warmup moves and drills.
While the target audience is young players and coaches; the adult player can learn a lot.
You can even search around the rest of the site and find videos on common sports injuries and like elbow, wrist and knee and how to tape properly.
Enjoy!